Timescales of spherulite crystallization in obsidian inferred from water concentration profiles

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ERRATUM Diffusion-controlled spherulite growth in obsidian inferred from H2O concentration profiles

Spherulites are spherical clusters of radiating crystals that occur naturally in rhyolitic obsidian. The growth of spherulites requires diffusion and uptake of crystal forming components from the host rhyolite melt or glass, and rejection of non-crystal forming components from the crystallizing region. Water concentration profiles measured by synchrotron-source Fourier transform spectroscopy re...

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Diffusion-controlled spherulite growth in obsidian inferred from H2O concentration profiles

Spherulites are spherical clusters of radiating crystals that occur naturally in rhyolitic obsidian. The growth of spherulites requires diffusion and uptake of crystal forming components from the host rhyolite melt or glass, and rejection of non-crystal forming components from the crystallizing region. Water concentration profiles measured by synchrotron-source Fourier transform spectroscopy re...

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Vesiculation rates of obsidian domes inferred from H2O concentration profiles

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Spherulite crystallization induces Fe-redox redistribution in silicic melt

Rhyolitic obsidians from Krafla volcano, Iceland, record the interaction between mobile hydrous species liberated during crystal growth and the reduction of ferric iron in the silicate melt. We performed synchrotron μ-FTIR and μ-XANES measurements along a transect extending from a spherulite into optically distinct colorless and brown glass zones. Measurements show that the colorless glass is e...

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ژورنال

عنوان ژورنال: American Mineralogist

سال: 2008

ISSN: 0003-004X

DOI: 10.2138/am.2008.2904